| A Relation Between Compatibility and Hysteresis and Its Role in the Search for New Smart Materials |
| Richard D. James, University
of Minnesota We present some recent measurements of hysteresis, in materials undergoing
big first order phase transformations, that resulted from a systematic
program of tuning of the lattice parameters by changing composition. The
lattice parameters were tuned so that a certain nongeneric condition of
compatibility between phases was satisfied. An exceptionally sharp drop
of size of the hysteresis of the transformation was observed at the special
lattice parameters. The data has some fascinating features, including an
apparent singularity. We re-examine the origins of hysteresis in light
of these measurements, commenting in particular on a) the relation between
static and thermodynamic approaches to hysteresis, b) the role of defects
and pinning, c) the relation between hysteresis and fatigue life under
repeated transformation, and d) the use of this kind of tuning to discover "unlikely" new
materials. The relation between hysteresis and reversibility, together
with the known extreme sensitivity of electromagnetic properties to lattice
parameters, suggests that materials with unexpected properties may be discovered
by this kind of tuning. Joint work with Jerry Zhang and Stefan Mueller. |